Articles: Department of Physical Sciences

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Browsing Articles: Department of Physical Sciences by Subject "Adsorption"

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    Determination of Potassium Levels in Intensive Subsistence Agricultural Soils in Nyamira County, Kenya
    (2013) Kenyanya, Omanga; Wachira, Jackson M.; Mbuvi, Harun
    Assessment of potassium levels in agricultural soils of Nyamira County, Kenya was necessitated by the observed progressive drops in maize acreage yields over the years despite use of phosphorus and nitrogenous fertilizers. In the study, concentration levels of potassium and other soil fertility indices such as, organic carbon, cation exchange capacity, exchangeable cations, soil pH, available nitrogen, total and available phosphorus were determined. Five composite soil samples were collected at depths of between 0-30 cm from five farms that have consistently been under intensive cultivation. Fractionation of potassium was achieved by sequential extraction of soil sampleswith distilled water, ammonium acetate and nitric acid in that order. Concentration levels of potassium in the extracts were determined using a flame photometer. Potassium concentration levels obtained from the water soluble soil extracts were used to calculate thermodynamic parameters such as free energy of replacement, potassium activity ratio and ionic strength of the soil solution. The relationship between the adsorbed and equilibrium potassium concentration, quantity/intensity was determined by plotting Freundlich adsorption isotherms. The isotherm was used to determine the buffering capacity ofpotassium and the concentration levels of potassium adsorbed on un-specific sites in the soil. The suitability of the adsorption equation was determined by applying the least square regression analysis. From the study available potassium in the soils ranged from 57 to 70 mg/kg and had amean value of 60±5.54.2 mg/kg (ammonium acetate method). The water soluble potassium ranged from 1.8 to 2.2 mg/kg with a mean of 2.02±0.16 mg/kg. Nitric acid extracted potassium had a mean of 149.±2.306 mg/kg. The mean free energy of replacement, Δ𝐹𝐹, was found to be −3572±44.98 cal/mol indicating that the soils have low supplying power of potassium. The potassium buffering capacity of the soils was found to have a mean of 1.189±0.06 mg/kg. The amount of potassium adsorbed on un-specific sites of the soilshad a mean value of 6.993±2.378 L/kg. These findingsreveal the extent of potassium depletionin the soils of this region and will form a baseline for working acreage potassium doses required for remediation.
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    Equilibrium Studies for Adsorption of Zn2+ on to Acid Treated Kikuyu Grass Pennisetum Clandestinum Biomass
    (2016-04) Murithi, Genson; wa-Thiong’o, Karanja; Wachira, Jackson M.
    The feasibility of using Pennisetum clandestinum biomass as low-cost adsorbent for the removal of Zn2+ was investigated in batch studies. The Freundlich, Langmuir,Dubinin Raduskevich and Temkin adsorption isotherms were used to analyze the experimental data. The kinetic analyses of the adsorption processes were performed using pseudo-first order and pseudo-second order kinetic models. The Langmuir isotherm adequately described the adsorption of Zn2+ onto the material. The maximum adsorption capacity max q was found to be 25.34 Mg/g. The Langmuir dimensionless constant, separation factor (RL) was between 0